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Department of Education, 
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Technická 5
166 28 Prague 6 – Dejvice
IČO: 60461373 / VAT: CZ60461373

Czech Post certified digital mail code: sp4j9ch

Copyright: UCT Prague 2015
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Project aimes

The main aim of the project is to contribute to the research on application of Carbon capture and storage (CCS) in the Czech Republic. In accordance with the requirements of the European Commission and the SET-Plan (European Strategic Energy Technology Plan) the specific aim of the project is focused on (i) the research and the verification of CO2 capture technologies using high-temperature carbonate loops in laboratory conditions and (ii) the preparation of pilot plant design documentation for its construction on this principle. At the same time, the project contributes to the creation of a knowledge- and personnel-base for CCS processes in the Czech Republic.

Outline of the high temperature carbonate looping process

Outline of the high temperature carbonate looping process

 

Project Activities

A – Project Management

B - Analysis of current state of the research and development on the field of high temperature carbonate looping

  1. Specification of the main outstanding problems of CO2 removal from the flue gas using the process of high-temperature sorption.
  2. Selection, definition and justification of problems for the solution in the framework of the proposed project. Clarification of the factual content of the project and the project goals.

C - Experimental research of carbonate looping and appropriate sorbents using model gas mixtures in laboratory conditions

  1. Testing different types of limestones from the perspective of their potential use in high-temperature carbonate loop. The temperature of decomposition and its influence on the adsorbent surface, changing of adsorbent surface to temperature and reactivity of CaO with CO2 at various temperatures will be investigated.
  2. Selection of optimal limestones for further testing in the laboratory facilities representing high temperature carbonate loop, the determination of the optimal working conditions of high-temperature carbonate loop.
  3. Design and construction of a high-temperature fluid laboratory apparatus for carbonate loop working with model gas N2 + CO2 and subsequent verification of the working conditions.
  4. Verification of laboratory apparatus operation and testing of selected adsorbents.
  5. Evaluation of the test results and the determination of the optimum working parameters for high temperature carbonate loop.
  6. Preliminary estimation of economic aspects for carbonate loop.

D - Design of pilot facility concept for research of flue gas decarbonatation using high-temperature looping.

  1. Research and selection of the concept of the energy section of the pilot facility for research high-temperature sorption of CO2 from flue gas by using carbonate loop. Specification input conditions and parameters for adsorption-desorption process.
  2. Research and development of the concept of a pilot system for the implementation of the process of carbonate loops for high-temperature CO2 sorption from flue gas. Preliminary layout of the system, the preliminary draft of the main components. The system dimensioning and preliminary chemical and thermal calculations in relation to the power source.
  3. The detailed calculations of the system. Proposals of the calculation models and system calculations. Calculations of the chemical base of the whole system of high temperature sorption, comparison of analytical results with laboratory tests, physics-technical and thermal calculations, calculations of mass and energy flows of the working media.
  4. Mathematical model of the high temperature sorption system. Development of calculation model of circulating fluidized bed high-temperature sorption Inc. verification of laboratory experiments. Calculations of fluid system, taking into account the different physics-chemical characteristics of sorbents.
  5. Design of the pilot system on the basis of detailed calculations, specification of the parameters of sorption processes.
  6. The proposal of measured parameters, method of measurement and visualization of measured parameters.
  7. The proposal for the management and safe operation of the pilot plant.

E - Documentation for the construction of a pilot plant for research of flue gas decarbonatation by using of the high temperature carbonate loop process.

  1. Elaboration of project and design documentation for the construction of a pilot facility.
  2. Processing specifications for the selection and purchase of components of a commercial character. Design of measuring positions and the requirements on the characteristics of sensors, processing specifications for purchase.
  3. Processing of tender documentation for the control unit of the pilot equipment and documentation for the connection with the user interface at the PC.
  4. Development of control software and software for evaluation and visualization.

F - LCA - life cycle assessment and determination of the carbon footprint of high temperature carbonate loop process by the use of LCA

  1. An appropriate characterization model will be developed based on the results of the pilot plant operation and the potential environmental impacts will be assessed
  2. Collection of inventory data will be performed and a functional and dynamic model of the life cycle of the high-temperature carbonate loop will be created using the LCA software GaBi (PE international)
  3. Potential environmental impacts of the carbonate loop operation will be classified and characterized using the LCA model
  4. It will be determined the total carbon footprint and GWP of the carbonate loop operation
  5. Structuring table(s) will be created from the LCA model. These tables point out the phases with positive and negative impacts throughout the life cycle of the carbonate loop.
  6. The effect of variable operation parameters and resulting environmental impacts will be studied. Measures will be proposed to reduce these environmental impacts

G – Overview of industrial sources, emitting CO2 and suitable for application of the technology of high temperature carbonate loop

  1. Acquisition of data from countrywide databases of air polluters and its completing using information sources of CHMI.
  2. Extension of the primary database by smaller sources at the regional level.
  3. Providing a summary of the technical parameters for each source, involved within wider primary overview of the polluters. Particularly following technical parameters are assessed: geographic location, age of the technology and its lifetime, terrain disposition and used technology.
  4. Removing such polluters, which obviously don´t accomplish criteria for successful implementation of the carbonate loop, from the primary list.
  5. Assessment of the selected sources in situ.
  6. Individual assessment of all the polluters, involved within the pre-selected list, on the basis of defined set of detailed criteria.
  7. Creation of the final database of the CO2 sources, best compatible for application of the carbonate loop.

H - Investigation of structural materials for the high-temperature carbonate loop technology

  1. Proposal of the experimental device with regard to requirements of high-temperature corrosion tests in the specific gas atmosphere typical for the high temperature carbonate loop
  2. Identification and procurement of the components for new experimental device.
  3. Construction and verification of the device and its preparation for the first test
  4. Identification of suitable structural materials for testing in carbonate loop, survey of availability of selected materials, procurement of available materials for production of specimens
  5. Proposal of testing methodology, production of specimens with regard to the methodology, sample holders procurement/production
  6. Performance of the first corrosion test of selected materials
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Hitecarlo (Research of high temperature CO2 sorption from flue gas using carbonate loop) is the research project with participation of three organizations with technical and engineering focus: UCT Prague, CTU and ÚJV Řež, a.s. UCT Prague is the project coordinator and together with two other partners CTU and ÚJV Řež, a.s. forms the consortium that utilizes synergies in expertise of individual research groups to achieve the aims of the project. Consortium members and their main tasks in the project are described below.

originál

University of Chemistry and Technology Prague (UCT Prague)

Project Coordinator:

      Assoc. Prof. Karel Ciahotný
      Department of Gas, Coke and Air Protection
      University of Chemistry and Technology Prague
      Technická 5, 166 28 Praha 6 – Dejvice
      e-mail:Karel.Ciahotny@vscht.cz
      Tel.: (+420) 22044 4228

Main tasks in the project:

Leading of four project activities: A – Project Management, B – Analysis of current state of the research and development on the field of high temperature carbonate looping, – Experimental research of carbonate looping and appropriate sorbents using model gas mixtures in laboratory conditions.

Participating in activity D – Design of pilot facility concept for research of flue gas decarbonatation using high-temperature looping.

originál

Czech Technical University in Prague (CTU)

Responsible person:

      Ing. Jan Hrdlička, Ph.D.
      Faculty of Mechanical Engineering
      Czech Technical University
      Technická 1902/4, 166 07 Praha 6
      e-mail: jan.hrdlicka@fs.cvut.cz
      Tel.: (+420) 224357974

Main tasks in the project:

Leading of project activity D – Design of pilot facility concept for research of flue gas decarbonatation using high-temperature looping.

Participating in activity E – Documentation for the construction of a pilot plant for research of flue gas decarbonatation by using of the high temperature carbonate loop process.

 logo ÚJV Řež

ÚJV Řež, a.s.

Responsible person:

      Ing. Olga Ubrá, DrSc.
      ÚJV Řež, a.s.
      Hlavní 130, 25068 Husinec- Řež
      e-mail: olga.ubra@ujv.cz
      Tel.: (+420) 226172372

Main tasks in the project:

Leading of project activity E – Documentation for the construction of a pilot plant for research of flue gas decarbonatation by using of the high temperature carbonate loop process.

Participating in activities B – Analysis of current state of the research and development on the field of high temperature carbonate looping, D – Design of pilot facility concept for research of flue gas decarbonatation using high-temperature looping.

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Project Research of horigináligh temperature CO2 sorption from flue gas using carbonate loop (acronym HITECARLO) is supported by Norway grants 2009 – 2014 in the frame of Programme CZ08 "Pilot Studies and Surveys on CCS Technology". Programme Operator is Ministry of Finance of the CR. Three Czech organizations are involved in the project – UCT Prague, CTU and ÚJV Řež a.s.

Project number: NF-CZ08-OV-1-005-01-2015

Project duration: 23 January 2015 – 30 April 2017

Total project budget: 26 685 559 CZK

Total grant: 20 219 265 CZK

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Posters

  • 9th Trondheim Conference on CO2 Capture, Transport and Storage, TCCS-9, 12. – 14. June 2017
    • L. Jílková, V. Vrbová, K. Ciahotný: Sorption Capacity of Natural Czech Limestones for Use in Carbonate Loop - (pdf, 946 kB)
    • V. Vrbová, L. Jílková, K. Ciahotný: Testing of Several Types of Limestone for Cycles High Temperature Sorption of CO2 - (pdf, 283 kB)
    • B. Miklová, M. Staf, V. Vrbová: Capture of CO2 on hydrotalcite-like compounds in fluidized and fixed-bed reactor - (pdf, 194 kB)
  • Týden výzkumu a inovací pro praxi a životní prostředí - TVIP 2017, 21. – 23. March 2017, J. Petrů, J. Poláčková: Konstrukční materiály pro technologie CCS - (pdf, 1.33MB) (in Czech language)
  • 5th Annual International Conference on Sustainable Energy and Environmental Sciences, Singapur, 22 - 23 February 2016 
    • V. Vrbová:  High Temperature Sorption of CO2 from Flue Gases Using Carbonate Loop - (pdf, 785 kB)
    • L. Jílková: Suitable Limestones for Removal of CO2 from Flue Gases Using High Temperature Carbonate Looping Technology - (pdf, 960 kB)
  • 8th Trondheim Conference on CO2 Capture, Transport and Storage, TCCS-8, Norway, 16 – 18 June 2015
    • Staf M., Ciahotný K.: Assessing of applicability of various limestones in high temperature carbonate looping technology - (pdf, 3.15MB)
    • Jílková L.,Vrbová V., Ciahotný K.: Testing of different materials using sorption system quantachrome asiq - (pdf, 884kB)
    • J. Hrdlicka, P. Skopec, J. Opatril, T.Dlouhy: Oxyfuel combustion in a bubbling fluidized bed combustor - (pdf, 1.74MB)
    • Vávrová J., Štefanica J., Kočí V., Machač P., Pilař L.: Environmental gains and impacts of a CCS technology - (pdf, 351kB)
  • 3rd International Conference on Chemical Technology  (ICCT 2015), 13 – 15 April 2015, Mikulov
    •       J. Vávrová, Štefanica, V. Kočí, P. Machač, L. Pilař: Environmental gains and impacts of a CCS technology - (pdf, 356kB)
  • Launch Conference of Programme CZ08 "Pilot Studies and Surveys on CCS Technology", Norway Grants 2009 – 2014, April 8th 2015, Pragu; Karel Ciahotný et al.: Research of high temperature CO2 sorption from flue gas using carbonate loop - (pdf, 690kB)

Presentations

  • 1st International Conference on Environmental Technology and Innovations (ICETI 2016), Ho Chi Minh City, 23. - 25. listopadu 2016, V. Kočí: Current needs for further developments toward a Circular Economy – specifically in the Central European Region - (pdf, 3,21MB)
  • 5th Annual International Conference on Sustainable Energy and Environmental Sciences, Singapur, 22 - 23 February 2016
    • K. Zakuciova: Life Cycle Assessment Overview of Carbon Capture and Storage Technologies - (pdf, 414kB)
    • J. Rocha: CCS Towards Sustainability, Social and environmental impacts by LCA approach- (pdf, 211kB)
    • M. Staf: Suppression of natural limestones deactivation during cyclic carbonation carbonation-decarbonation process in CCS technology - (pdf, 2.93MB)
    • V. Kočí: The concept of Circular Economy applied to CCS, Waste and Wastewater Treatment Technologies - (pdf, 3.93MB)
  • German – Czech Seminar, TU Bergakakademie Freiberg, Germany, 8 December 2015, M. Staf: Application of natural limestones in technology of high-temperature sorption of CO2 from flue gas - (pdf, 7.38MB)
  • Conference CHISA 2015, Hotel Jezerka, dam Seč, Czech Republic, 9 -12 November 2015; M. Staf, K. Ciahotný, T. Hlinčík: Použití přírodních vápenců z lomů v České republice v technologii vysokoteplotní sorpce oxidu uhličitého ze spalin -(pdf, 3.56MB) (in Czech language)
  • Energie z biomasy XVI (Energy from biomass XVI), Lednice, Czech Republic, 16 – 18 September 2015; P. Skopec, J. Hrdlička, M.Vodička.: Zkušenosti s oxy-fuel spalováním ve stacionární fluidní vrstvě - (pdf, 733kB) (in Czech language)
  • 8th Trondheim Conference on CO2 Capture, Transport and Storage, TCCS-8, Norway, 16 – 18 June 2015; J. Hrdlicka, P. Skopec, J. Opatril, T.Dlouhy: Oxyfuel combustion in a bubbling fluidized bed combustor - (pdf, 891MB)
  • 6th periodic meeting of activity leaders at UCT Prague; 29.5. 2015 Prague; M. Staf: Tests of CaO reactivity realized on the apparatus with fixed bed adsorber -  (pdf, 1.0MB)
  • 3rd International Conference on Chemical Technology (ICCT 2015), 13 – 15 April 2015, Mikulov, K. Ciahotný, M. Staf, T. Hlinčík, V. Vrbová, V. Tekáč, I. Jiříček: Vysokoteplotní karbonátová smyčka – moderní metoda odstraňování CO2 ze spalin - (pdf, 871kB) (in Czech language)
  • Launch Conference of Programme CZ08 "Pilot Studies and Surveys on CCS Technology",
    Norway Grants 2009 – 2014, April 8th 2015, Prague; Karel Ciahotný: Research of high temperature CO2 sorption from flue gas using carbonate loop - (pdf, 871kB) (in Czech language)

Papers

  • Týden výzkumu a inovací pro praxi a životní prostředí - TVIP 2017, 21. – 23. března 2017, M. Staf: Testování vysokoteplotní sorpce CO2v laboratorní fluidní aparatuře - (pdf, 2MB) (in Czech language)
  • 1st International Conference on Environmental Technology and Innovations (ICETI 2016), Ho Chi Minh City, 23. - 25. listopadu 2016, V. Kočí: Current needs for further developments toward a Circular Economy – specifically in the Central European Region - (pdf, 112kB)
  • M. Staf, V. Vrbová, L. Jílková, B. Miklová: REGENERACE SORPČNÍ KAPACITY VÁPENCŮ PRO ZÁCHYT CO2 ZAVÁDĚNÍM VODNÍ PÁRY, Paliva 8 (2016), 2., pp. 66 – 77. - (pdf, 1,31MB) (in Czech language)
  • Petrů, J.; Poláčková, J.; Marušáková, D.; Kubásek, J. Carbon Capture and Storage Technologies. Materials, Methods & Technologies [Online] 201610, 51-57. http://www.scientific-publications.net/en/article/1001129/(pdf, 634 kB)
  • M. Staf, K. Ciahotný, E. Krtková: PERSPEKTIVY APLIKACE KARBONÁTOVÉ SMYČKY V PRŮMYSLU A ENERGETICE ČESKÉ REPUBLIKY - (pdf, 656 kB) (in Czech language)
  • I. Jiříček, J. Farták, V. Obrdlíková, K. Ciahotný, P. Machač: KAPACITA KALCINÁTŮ A HYDRÁTŮ VÁPENCŮ PRO ZÁCHYT VLHČENÉHO OXIDU UHLIČITÉHO - (pdf, 842 kB) (in Czech language)
  • K. Zakuciova: Life Cycle Assessment Overview of Carbon Capture and Storage Technologies - (pdf, 460 kB)
  • V. Kočí: The concept of Circular Economy applied to CCS, Waste and Wastewater Treatment Technologies - (pdf, 65 kB)
  • K. Ciahotný, M. Staf, T. Hlinčík, V. Vrbová, L. Jílková, S. Randáková: REMOVING CARBON DIOXIDE FROM FLUE GAS USING HIGH TEMPERATURE CARBONATE LOOPING, Paliva 7 (2015), 4., pp. 84 – 90. - (pdf, 600,5 kB)
  • J. Poláčková, J. Petrů, J. Berka, D. Maruščáková: PŘÍPRAVA EXPERIMENTÁLNÍHO ZAŘÍZENÍ PRO VYSOKOTEPLOTNÍ EXPOZICE MATERIÁLŮ TECHNOLOGIÍ CCS, Paliva 7 (2015), 4., str. 100 – 104. - (pdf, 370 kB) (in Czech language)

Video

Experimental simulation of low-temperature fluid layer

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 originál

University of Chemistry and Technology Prague (UCT Prague)

      Project Coordinator:

            Assoc. Prof. Karel Ciahotný
            Department of Gas, Coke and Air Protection
            University of Chemistry and Technology Prague
            Technická 5, 166 28 Praha 6 – Dejvice
            e-mail: Karel.Ciahotny@vscht.cz
            Tel.: (+420) 22044 4228

      Project manager:

            Ing. Karolína Friessová, Ph.D.,
            e-mail: karolina.friessova@vscht.cz

      Financial manager:

            Ing. Jana Hrušková
            e-mail: Jana.Hruskova@vscht.cz

      RTD manager:

            Mgr. Helena Doležalová
            e-mail: Helena.Matejekova@vscht.cz

 originál

Czech Technical University in Prague (CTU)

      Research manager:

            Ing. Jan Hrdlička, Ph.D.
            Faculty of Mechanical Engineering
            Czech Technical University
            Technická 1902/4, 166 07 Praha 6
            e-mail: jan.hrdlicka@fs.cvut.cz
            Tel.: (+420) 224357974

      Project manager:

            Mgr. Pavlína Chánová
             e-mail: pavlina.chanova@fs.cvut.cz

      Financial manager:

            Ing. Monika Vitvarová
             e-mail: Monika.Vitvarova@fs.cvut.cz

 originál

ÚJV Řež, a.s.

      Research manager:

            Ing. Olga Ubrá, DrSc.
            Hlavní 130, 25068 Husinec- Řež
            e-mail: olga.ubra@ujv.cz
            Tel.: (+420) 226172372

      Financial manager:

            Ing. Lenka Hudcová
            e-mail: Lenka.Hudcova@ujv.cz

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    [nazev] => Konference GHGT-13
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Venue: The SwissTech Convention Center, Lausanne, Switzerland

Date: 14 – 18 November 2016

Our contribution:

Lecture:

  • J. Hrdlicka, J. Opatřil, M. Vodička, P. Skopec, L. Pilař, M. Staf: Modelling of Ca-looping for a 250 MWe lignite coal fired power plant - (pdf, 130kB)

Participation in the Conference was supported by a grant (NF-CZ08-BFB-1-019-2016) from the Fund for Bilateral Cooperation on programme level – measure “B” under the programme CZ08.

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Copyright: UCT Prague 2015
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